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  7. 2-[N,N-Bis(trifluoromethylsulfonyl)amino]-5-chloropyridine, 99%

2-[N,N-Bis(trifluoromethylsulfonyl)amino]-5-chloropyridine, 99%

Codice prodotto. 11383836
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Quantità:
1 g
5 g
Dimensione della confezione:
1g
5g
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Codice prodotto. 11383836

Marca: Thermo Scientific Alfa Aesar L16929.06

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Descrizione

CAS: 145100-51-2 | C7H3ClF6N2O4S2 | 392.671 g/mol

2-[N,N-Bis(trifluoromethylsulfonyl)amino]-5-chloropyridine provides good yields of vinyl triflates from the corresponding ketone enolates or dienolates. It is used in the total synthesis of (-)-porantheridine and the trans decahydroquinoline alkaloid (+)-219A. It is also used as a reactant for Suzuki-Miyaura cross coupling, synthesis of nicotinic acetylcholine receptor-selective ligands, enantioselective desymmetrizing palladium catalyzed carbonylation reactions, synthesis of high affinity niacin receptor GPR109A agonists and in preparation of heteroaromatics.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
2-[N,N-Bis(trifluoromethylsulfonyl)amino]-5-chloropyridine provides good yields of vinyl triflates from the corresponding ketone enolates or dienolates. It is used in the total synthesis of (-)-porantheridine and the trans decahydroquinoline alkaloid (+)-219A. It is also used as a reactant for Suzuki-Miyaura cross coupling, synthesis of nicotinic acetylcholine receptor-selective ligands, enantioselective desymmetrizing palladium catalyzed carbonylation reactions, synthesis of high affinity niacin receptor GPR109A agonists and in preparation of heteroaromatics.

Solubility
Reacts with water.

Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store under dry inert gas. It is sensitive to moisture.
TRUSTED_SUSTAINABILITY

Identificatori chimici

CAS 145100-51-2
Formula molecolare C7H3ClF6N2O4S2
Molecular Weight (g/mol) 392.671
Numero MDL MFCD00191833
InChI Key TUFGVZMNGTYAQD-UHFFFAOYSA-N
Sinonimo 2-n,n-bis trifluoromethylsulphonyl amino-5-chloropyridine, 2-n,n-bis trifluoromethanesulfonyl amino-5-chloropyridine, comins' reagent, n-5-chloro-2-pyridyl triflimide, 2-n,n-bis trifluoromethylsulfonyl amino-5-chloropyridine, comins triflating reagent, n-5-chloro-2-pyridyl bis trifluoromethanesulfonimide, n-5-chloropyridin-2-yl-1,1,1-trifluoro-n-trifluoromethylsulfonyl methanesulfonamide, n-5-chloropyridin-2-yl triflimide, n-5-chloropyridin-2-yl-1,1,1-trifluoro-n-trifluoromethyl sulfonyl methanesulfonamide
PubChem CID 388544
IUPAC Name N-(5-chloropyridin-2-yl)-1,1,1-trifluoro-N-(trifluoromethylsulfonyl)methanesulfonamide
SMILES C1=CC(=NC=C1Cl)N(S(=O)(=O)C(F)(F)F)S(=O)(=O)C(F)(F)F

Specifica

Materiale o nome chimico 2-[N,N-Bis(trifluoromethylsulfonyl)amino]-5-chloropyridine
Punto di fusione 44°C to 47°C
Quantità 5 g
Beilstein 5833971
Sensibilità Moisture sensitive
Informazioni di solubilità Reacts with water.
Peso formulazione 392.68
Percent Purity 99%

RUO – Research Use Only

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