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tert-Butyl hydroperoxide, 70% aq. soln., Thermo Scientific Chemicals
Descrizione
tert-Butyl hydroperoxide is used as an initiator for radical polymerization and in various oxidation process such as sharpless epoxidation. It is involved in osmium catalyzed vicinal hydroxylation of olefins under alkaline conditions. Furthermore, it is used in catalytic asymmetric oxidation of sulfides to sulfoxides using binaphthol as a chiral auxiliary and in the oxidation of dibenzothiophenes. It plays an important role for the introduction of peroxy groups in organic synthesis.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
tert-Butyl hydroperoxide is used as an initiator for radical polymerization and in various oxidation process such as sharpless epoxidation. It is involved in osmium catalyzed vicinal hydroxylation of olefins under alkaline conditions. Furthermore, it is used in catalytic asymmetric oxidation of sulfides to sulfoxides using binaphthol as a chiral auxiliary and in the oxidation of dibenzothiophenes. It plays an important role for the introduction of peroxy groups in organic synthesis.
Solubility
Miscible with water and diethyl ether.
Notes
Light sensitive. Store in cool place. Incompatible with powdered metals, strong oxidizing agents, reducing agents, acids, alkalis and heavy metals.
Specifica
Specifica
Materiale o nome chimico | tert-Butyl hydroperoxide |
Punto di fusione | -3°C |
Densità | 0.937 |
Punti di ebollizione | 96°C (decomposition) |
Punto d'infiammabilità | 43°C (109°F) |
Intervallo percentuale saggio | 70% Aqueous Solution |
Formula lineare | (CH3)3COOH |
Indice di rifrazione | 1.387 |
Quantità | 100 mL |
Numero UN | UN3109 |
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Sicurezza e movimentazione
- cancerogenicità Categoria 2
- Sensibilizzazione della pelle Categoria 1
- H331-Tossico se inalato.
- H351-Sospettato di provocare il cancro.
RUO – Research Use Only