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1,5-Cyclooctadiene(pyridine)(tricyclohexylphosphine)iridium(I) hexafluorophosphate, 99%, Thermo Scientific Chemicals

Codice prodotto. 11359717
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Quantità:
250 mg
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Descrizione

 

1,5-Cyclooctadiene(pyridine)(tricyclohexylphosphine)iridium(I) hexafluorophosphate is used as a catalyst for hydrogenation of mono-, di-, tri-, and tetra-substituted substrates and the isomerization and hydroboration of alkenes. It is also used in isotope exchange reactions, especially the direct exchange of a hydrogen atom with its isotopes deuterium and tritium. Carbonyl groups are also known to direct the hydrogenation by the Crabtree catalyst is highly regioselective.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

TRUSTED_SUSTAINABILITY

Specifica

Materiale o nome chimico 1,5-Cyclooctadiene(pyridine)(tricyclohexylphosphine)iridium(I) hexafluorophosphate
CAS 64536-78-3
Punto di fusione 175°C (decomposition)
Formula molecolare C31H50F6IrNP2
Numero MDL MFCD00075097
Quantità 250 mg
Sensibilità Moisture sensitive
Sinonimo crabtree's catalyst, unii-816rs2nbpn, 816rs2nbpn, 1,5-cyclooctadiene pyridine tricyclohexylphosphine iridium hexafluorophosphate, iridium i hexafluorophosphate, 1,5-cyclooctadiene pyridine tricyclohexylphosphine iridium i hexafluorophosphate, tricyclohexylphosphine 1,5-cyclooctadiene pyridine iridium i hexafluorophosphate, felkin-crabtree catalyst, crabtree's catalyst mi, crabtree's catalyst hexafluorophosphate
Informazioni di solubilità Slightly soluble in acetone,dichloromethane,ethanol and diethyl ether; Insoluble in water.
InChI Key UJXHUUQZACSUOG-KJWGIZLLSA-N
SMILES [Ir+].C1=CC=NC=C1.F[P-](F)(F)(F)(F)F.C1C\C=C/CC\C=C/1.C1CCC(CC1)P(C1CCCCC1)C1CCCCC1
IUPAC Name (1Z,5Z)-cycloocta-1,5-diene;iridium;pyridine;tricyclohexylphosphane;hexafluorophosphate
Molecular Weight (g/mol) 804.90
PubChem CID 5702647
Peso formulazione 804.89
Percent Purity 99%
Forma fisica Crystalline Powder
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