missing translation for 'onlineSavingsMsg'
Learn More
  1. Home
  2. Products
  3. Chemicals
  4. Organic compounds
  5. Organic metal halides
  6. Allylpalladium(II) chloride dimer, Pd 56.0% min, Thermo Scientific Chemicals

Allylpalladium(II) chloride dimer, Pd 56.0% min, Thermo Scientific Chemicals

Catalog Number p-7048276
Click to view available options
Quantità:
0.25 g
1 g
5 g
Les retours ne sont pas autorisés pour ce produit. Consulta la politica di reso
12012-95-2
C6H10Cl2Pd2
365.89
MFCD00044874
PENAXHPKEVTBLF-UHFFFAOYSA-L
allylpalladium chloride dimer, bis allyl dichlorodipalladium, diallyldipalladium dichloride, palladium allyl chloride dimer, diallydichlorodipalladium, pi-allyl palladium chloride, allylpalladium ii chloride, bis chloro-pi-allylpalladium, allyl palladium chloride dimer, bis pi-allyl chloropalladium
61538
chloropalladium(1+);prop-1-ene
Cl[Pd].Cl[Pd].c:c:c.c:c:c
Les retours ne sont pas autorisés pour ce produit. Consulta la politica di reso
12012-95-2
C6H10Cl2Pd2
365.89
MFCD00044874
PENAXHPKEVTBLF-UHFFFAOYSA-L
allylpalladium chloride dimer, bis allyl dichlorodipalladium, diallyldipalladium dichloride, palladium allyl chloride dimer, diallydichlorodipalladium, pi-allyl palladium chloride, allylpalladium ii chloride, bis chloro-pi-allylpalladium, allyl palladium chloride dimer, bis pi-allyl chloropalladium
61538
chloropalladium(1+);prop-1-ene
Cl[Pd].Cl[Pd].c:c:c.c:c:c

Descrizione

Allylpalladium(II) chloride dimer is used as an important catalyst in Heck reaction. It reacts with cyclopentadienyl anion to give cyclopentadienyl allyl palladium. It acts as a precatalyst for asymmetric and cross-coupling catalysis. Further, it is used in the preparation of 1,4-diallyl-1,2-dihydroisoquinolines. It is also employed as a catalyst for greener Buchwald-Hartwig coupling reaction and involved in the synthesis of cationic palladium catalysts. In addition, it takes part in preparation of -heterocyclic carbene-palladium-eta3-allyl chloride complex, which is an efficient catalyst for the Suzuki-Miyaura cross-coupling reactions in synthetic chemistry.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

TRUSTED_SUSTAINABILITY
Materiale o nome chimico Allylpalladium(II) chloride dimer
Punto di fusione 120°C (decomposition)
Colore Yellow
Quantità 0.25 g
Beilstein 4124623
Sensibilità Air and moisture sensitive
Informazioni di solubilità Very soluble in dichloromethane and dichloroethane; Slightly soluble in toluene,insoluble in waterSoluble in chloroform,benzene,acetone and dichloromethane,dichloroethane and methanol; Slightly soluble in toluene; Insoluble in water.
Peso formulazione 365.85
Concentration or Composition (by Analyte or Components) Pd 56.0% min.
Forma fisica Powder

Sicurezza e movimentazione

compliance-icons
Identificativo prodotto
  • di-.Mu.-chlor-bis(eta-allil)palladio
 Avvertenza
  • Attenzione
 Categoria di pericolo
  • Corrosione/irritazione della pelle Categoria 2
  • Lesione oculare grave/irritazione oculare Categoria 2
  • Tossicità specifica per organi bersaglio (esposizione singola) Categoria 3
 Indicazioni di pericolo
  • H315-Provoca irritazione cutanea.
  • H319-Provoca grave irritazione oculare.
  • H335-Può irritare le vie respiratorie.
 Consigli di prudenza
  • P261-Evitare di respirare la polvere/i fumi/i gas/la nebbia/i vapori/gli aerosol.
  • P280-Indossare guanti/indumenti protettivi/Proteggere gli occhi/il viso.
  • P305+P351+P338-IN CASO DI CONTATTO CON GLI OCCHI: sciacquare accuratamente per parecchi minuti. Togliere le eventuali lenti a contatto se è agevole farlo. Continuare a sciacquare.
  • P304+P340-IN CASO DI INALAZIONE: trasportare l'infortunato all'aria aperta e mantenerlo a riposo in posizione che favorisca la respirazione.
  • P405-Conservare sotto chiave.
  • P501-Smaltire il prodotto/recipiente in .

RUO – Research Use Only

missing translation for 'provideContentCorrection'

missing translation for 'productTitle'

missing translation for 'byClickingSubmit' missing translation for 'privacyPolicy'.

Cancel missing translation for 'submit'