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Tris(dibenzylideneacetone)dipalladium(0), Pd 21.5% min, Thermo Scientific Chemicals
95.27€ - 382.91€
Identificatori chimici
CAS | 51364-51-3 |
---|---|
Formula molecolare | C51H42O3Pd2 |
Molecular Weight (g/mol) | 915.73 |
Numero MDL | MFCD00013310 |
InChI Key | CYPYTURSJDMMMP-UHFFFAOYSA-N |
Sinonimo | tris dibenzylideneacetone dipalladium 0, tris dibenzylideneacetone dipalladium, pd2 dba 3, tris dibezylideneacetone dipalladium, tris dibenzylideneacetone dipalladium o, tris dibenzylideneacetonyl bis-palladium, tris dba, tris 1e,4e-1,5-diphenylpenta-1,4-dien-3-one dipalladium |
PubChem CID | 9811564 |
IUPAC Name | (1E,4E)-1,5-diphenylpenta-1,4-dien-3-one;palladium |
SMILES | [Pd].[Pd].O=C(C=CC1=CC=CC=C1)C=CC1=CC=CC=C1.O=C(C=CC1=CC=CC=C1)C=CC1=CC=CC=C1.O=C(C=CC1=CC=CC=C1)C=CC1=CC=CC=C1 |
Codice del prodotto | Marca | Quantità | Prezzo | Quantità e disponibilità | |||||
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Codice del prodotto | Marca | Quantità | Prezzo | Quantità e disponibilità | |||||
11397537
|
Thermo Scientific Alfa Aesar
012760.03 |
1 g |
95.27€
1g |
Effettua il login per acquistare questo articolo Hai bisogno di un conto web ? Registrati oggi stesso! | |||||
11307547
|
Thermo Scientific Alfa Aesar
012760.06 |
5 g |
382.91€
5g |
Effettua il login per acquistare questo articolo Hai bisogno di un conto web ? Registrati oggi stesso! | |||||
Descrizione
Tris(dibenzylideneacetone)dipalladium(0) is the most widely used Pd0 precursor complex in synthesis and catalysis, in particular as a catalyst for various coupling reactions. It is used as a catalyst precursor for palladium-catalyzed carbon-nitrogen bond formation, conversion of aryl chlorides, triflates and nonaflates to nitroaromatics. It is used as catalyst for the synthesis of epoxides, alpha-arylation of ketones, in combination with BINAP for the asymmetric heck arylation of olefins, site-selective benzylic sp3 palladium-catalyzed direct arylation and homoallylic diamination of terminal olefins. It also used for palladium-catalyzed one-pot synthesis of tricyclic indolines, in the Suzuki-Miyaura coupling of 2-pyridyl nucleophiles and cross-coupling of aryl halides with aryl boronic acids.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Identificatori chimici
51364-51-3 | |
915.73 | |
CYPYTURSJDMMMP-UHFFFAOYSA-N | |
9811564 | |
[Pd].[Pd].O=C(C=CC1=CC=CC=C1)C=CC1=CC=CC=C1.O=C(C=CC1=CC=CC=C1)C=CC1=CC=CC=C1.O=C(C=CC1=CC=CC=C1)C=CC1=CC=CC=C1 |
C51H42O3Pd2 | |
MFCD00013310 | |
tris dibenzylideneacetone dipalladium 0, tris dibenzylideneacetone dipalladium, pd2 dba 3, tris dibezylideneacetone dipalladium, tris dibenzylideneacetone dipalladium o, tris dibenzylideneacetonyl bis-palladium, tris dba, tris 1e,4e-1,5-diphenylpenta-1,4-dien-3-one dipalladium | |
(1E,4E)-1,5-diphenylpenta-1,4-dien-3-one;palladium |
Specifica
Tris(dibenzylideneacetone)dipalladium(0) | |
152°C to 155°C | |
MFCD00013310 | |
tris dibenzylideneacetone dipalladium 0, tris dibenzylideneacetone dipalladium, pd2 dba 3, tris dibezylideneacetone dipalladium, tris dibenzylideneacetone dipalladium o, tris dibenzylideneacetonyl bis-palladium, tris dba, tris 1e,4e-1,5-diphenylpenta-1,4-dien-3-one dipalladium | |
CYPYTURSJDMMMP-UHFFFAOYSA-N | |
(1E,4E)-1,5-diphenylpenta-1,4-dien-3-one;palladium | |
9811564 | |
Powder |
51364-51-3 | |
C51H42O3Pd2 | |
Air and moisture sensitive | |
Soluble in chlorinated solvents,benzene and THF. | |
[Pd].[Pd].O=C(C=CC1=CC=CC=C1)C=CC1=CC=CC=C1.O=C(C=CC1=CC=CC=C1)C=CC1=CC=CC=C1.O=C(C=CC1=CC=CC=C1)C=CC1=CC=CC=C1 | |
915.73 | |
915.74 |
Sicurezza e movimentazione
P261-P272-P280g-P302+P352-P333+P313-P363-P501c
H317
missing translation for 'tsca' : No
Recommended Storage : Ambient temperatures; Store under Argon
- Tris(dibenzylideneacetone)dipalladium(0), Pd 21.5% min
Avvertenza
- Attenzione
Categoria di pericolo
- Sensibilizzazione della pelle Categoria 1
Indicazioni di pericolo
- H317-Può provocare una reazione allergica cutanea.
Consigli di prudenza
- P280-Indossare guanti/indumenti protettivi/Proteggere gli occhi/il viso.
- P302+P352-IN CASO DI CONTATTO CON LA PELLE: lavare abbondantemente con acqua/.
- P333+P313-In caso di irritazione o eruzione della pelle: consultare un medico.
Informazioni supplementari
- MIXTURE LIST-Contiene: Tris(dibenzylideneacetone)dipalladium(0), Pd
RUO – Research Use Only