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Tris(dibenzylideneacetone)dipalladium(0), Pd 21.5% min, Thermo Scientific Chemicals

95.27€ - 382.91€

Identificatori chimici

CAS 51364-51-3
Formula molecolare C51H42O3Pd2
Molecular Weight (g/mol) 915.73
Numero MDL MFCD00013310
InChI Key CYPYTURSJDMMMP-UHFFFAOYSA-N
Sinonimo tris dibenzylideneacetone dipalladium 0, tris dibenzylideneacetone dipalladium, pd2 dba 3, tris dibezylideneacetone dipalladium, tris dibenzylideneacetone dipalladium o, tris dibenzylideneacetonyl bis-palladium, tris dba, tris 1e,4e-1,5-diphenylpenta-1,4-dien-3-one dipalladium
PubChem CID 9811564
IUPAC Name (1E,4E)-1,5-diphenylpenta-1,4-dien-3-one;palladium
SMILES [Pd].[Pd].O=C(C=CC1=CC=CC=C1)C=CC1=CC=CC=C1.O=C(C=CC1=CC=CC=C1)C=CC1=CC=CC=C1.O=C(C=CC1=CC=CC=C1)C=CC1=CC=CC=C1
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Prodotti 2
Codice del prodotto Marca Quantità Prezzo Quantità e disponibilità  
Codice del prodotto Marca Quantità Prezzo Quantità e disponibilità  
11397537
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Thermo Scientific Alfa Aesar
012760.03
1 g
95.27€
1g
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11307547
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Thermo Scientific Alfa Aesar
012760.06
5 g
382.91€
5g
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Descrizione

Descrizione

Tris(dibenzylideneacetone)dipalladium(0) is the most widely used Pd0 precursor complex in synthesis and catalysis, in particular as a catalyst for various coupling reactions. It is used as a catalyst precursor for palladium-catalyzed carbon-nitrogen bond formation, conversion of aryl chlorides, triflates and nonaflates to nitroaromatics. It is used as catalyst for the synthesis of epoxides, alpha-arylation of ketones, in combination with BINAP for the asymmetric heck arylation of olefins, site-selective benzylic sp3 palladium-catalyzed direct arylation and homoallylic diamination of terminal olefins. It also used for palladium-catalyzed one-pot synthesis of tricyclic indolines, in the Suzuki-Miyaura coupling of 2-pyridyl nucleophiles and cross-coupling of aryl halides with aryl boronic acids.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Specifica

Identificatori chimici

51364-51-3
915.73
CYPYTURSJDMMMP-UHFFFAOYSA-N
9811564
[Pd].[Pd].O=C(C=CC1=CC=CC=C1)C=CC1=CC=CC=C1.O=C(C=CC1=CC=CC=C1)C=CC1=CC=CC=C1.O=C(C=CC1=CC=CC=C1)C=CC1=CC=CC=C1
C51H42O3Pd2
MFCD00013310
tris dibenzylideneacetone dipalladium 0, tris dibenzylideneacetone dipalladium, pd2 dba 3, tris dibezylideneacetone dipalladium, tris dibenzylideneacetone dipalladium o, tris dibenzylideneacetonyl bis-palladium, tris dba, tris 1e,4e-1,5-diphenylpenta-1,4-dien-3-one dipalladium
(1E,4E)-1,5-diphenylpenta-1,4-dien-3-one;palladium

Specifica

Tris(dibenzylideneacetone)dipalladium(0)
152°C to 155°C
MFCD00013310
tris dibenzylideneacetone dipalladium 0, tris dibenzylideneacetone dipalladium, pd2 dba 3, tris dibezylideneacetone dipalladium, tris dibenzylideneacetone dipalladium o, tris dibenzylideneacetonyl bis-palladium, tris dba, tris 1e,4e-1,5-diphenylpenta-1,4-dien-3-one dipalladium
CYPYTURSJDMMMP-UHFFFAOYSA-N
(1E,4E)-1,5-diphenylpenta-1,4-dien-3-one;palladium
9811564
Powder
51364-51-3
C51H42O3Pd2
Air and moisture sensitive
Soluble in chlorinated solvents,benzene and THF.
[Pd].[Pd].O=C(C=CC1=CC=CC=C1)C=CC1=CC=CC=C1.O=C(C=CC1=CC=CC=C1)C=CC1=CC=CC=C1.O=C(C=CC1=CC=CC=C1)C=CC1=CC=CC=C1
915.73
915.74
Videos
Sicurezza e movimentazione

Sicurezza e movimentazione

P261-P272-P280g-P302+P352-P333+P313-P363-P501c

H317

missing translation for 'tsca' : No

Recommended Storage : Ambient temperatures; Store under Argon

Identificativo prodotto
  • Tris(dibenzylideneacetone)dipalladium(0), Pd 21.5% min

Avvertenza
  • Attenzione

Categoria di pericolo
  • Sensibilizzazione della pelle Categoria 1

Indicazioni di pericolo
  • H317-Può provocare una reazione allergica cutanea.

Consigli di prudenza
  • P280-Indossare guanti/indumenti protettivi/Proteggere gli occhi/il viso.
  • P302+P352-IN CASO DI CONTATTO CON LA PELLE: lavare abbondantemente con acqua/.
  • P333+P313-In caso di irritazione o eruzione della pelle: consultare un medico.

Informazioni supplementari
  • MIXTURE LIST-Contiene: Tris(dibenzylideneacetone)dipalladium(0), Pd

SDS
Documenti

Documenti

Product Certifications

RUO – Research Use Only